S1·E27 The Temple of Evil

The TARDIS arrives on Earth landing in 16th century Aztec society. Barbara goes off exploring - despite the Doctor's orders not to wander off - and is taken away by the high priest Autloc who believes she is the reincarnation of the goddess Yetaxa. They believe it is a sign that the rains - which are late - will now come. The high priest of sacrifice Tlotoxl recruits Ian to lead their army but he finds he has a rival in Ixta. Ian is less than comfortable with his role when he learns that they are to deliver the human sacrifice to the high priest at the rain ceremony. The Doctor emphasizes that they must not interfere with Aztec rituals, something that does not sit well with Barbara.